IndiumV3, Main, Repository, bibRecord, 002D09

Hydrogen from ethanol solution under UV-visible light. Photocatalysts produced by nitriding titanium nitride and indium oxide intimate mixtures to form Ti-In nitride composites

Identifieur interne : 002D09 ( Main/Repository ); précédent : 002D08; suivant : 002D10

Hydrogen from ethanol solution under UV-visible light. Photocatalysts produced by nitriding titanium nitride and indium oxide intimate mixtures to form Ti-In nitride composites

Auteurs : RBID : Pascal:11-0271100

Descripteurs français

Pascal (Inist)
- Hydrogène, Ethanol, Photocatalyse, Nitruration, Nitrure de titane, Oxynitrure, Oxyde d'indium, Matériau composite, Eau, Semiconducteur, Catalyse hétérogène, Protection environnement, Composé de métal de transition, Oxyde de titane, Composé binaire, Ammoniac, Haute température, Catalyseur, Spectrométrie photoélectron, Rayon X, Diffraction RX, Facteur réflexion, Aire superficielle, Dimension pore, Distribution, Caractérisation, TiO2, O Ti.
Wicri :
- concept : Hydrogène, Matériau composite, Eau.

English descriptors

KwdEn :
- Ammonia, Binary compound, Catalyst, Characterization, Composite material, Distribution, Environmental protection, Ethanol, Heterogeneous catalysis, High temperature, Hydrogen, Indium oxide, Nitrides oxides, Nitriding, Photocatalysis, Photoelectron spectrometry, Pore size, Reflectance, Semiconductor materials, Surface area, Titanium nitride, Titanium oxide, Transition element compounds, Water, X ray, X ray diffraction.

Abstract

Photocatalytic production of hydrogen gas from 20% ethanol-water was accomplished with Ti-In nitride composites. These materials were produced by nitriding a TiO₂ with ammonia at a high temperature, then adding In₂O₃ and further ammonolysis for different periods of time. The catalysts were very stable and continued to produce H₂ gas at 920 μmol h^-1 g^-1 for 50 h and accumulated 12.8 mmol H₂ gas. The water splitting photocatalytic reaction can be driven by UV-vis light, maximum producing H₂ gas at 1277 μmol h^-1 g^-1. It is critical that we understand how having high, stable activity is possible. We used XPS,X-ray (XRD), UV-vis diffuse reflectance spectrometry, and BET surface area and pore size distribution for further characterization.

Links toward previous steps (curation, corpus...)

to stream Main, to step Corpus: 003008

Links to Exploration step

Pascal:11-0271100

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Hydrogen from ethanol solution under UV-visible light. Photocatalysts produced by nitriding titanium nitride and indium oxide intimate mixtures to form Ti-In nitride composites</title>
<author><name sortKey="Kuo, Yenting" uniqKey="Kuo Y">Yenting Kuo</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Kansas State University</s1>
<s2>KS, 66506</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>États-Unis</country>
<placeName><region type="state">Kansas</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Klabunde, Kenneth J" uniqKey="Klabunde K">Kenneth J. Klabunde</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Kansas State University</s1>
<s2>KS, 66506</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>États-Unis</country>
<placeName><region type="state">Kansas</region>
</placeName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">11-0271100</idno>
<date when="2011">2011</date>
<idno type="stanalyst">PASCAL 11-0271100 INIST</idno>
<idno type="RBID">Pascal:11-0271100</idno>
<idno type="wicri:Area/Main/Corpus">003008</idno>
<idno type="wicri:Area/Main/Repository">002D09</idno>
</publicationStmt>
<seriesStmt><idno type="ISSN">0926-3373</idno>
<title level="j" type="abbreviated">Appl. catal., B  Environ.</title>
<title level="j" type="main">Applied catalysis. B, Environmental</title>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Ammonia</term>
<term>Binary compound</term>
<term>Catalyst</term>
<term>Characterization</term>
<term>Composite material</term>
<term>Distribution</term>
<term>Environmental protection</term>
<term>Ethanol</term>
<term>Heterogeneous catalysis</term>
<term>High temperature</term>
<term>Hydrogen</term>
<term>Indium oxide</term>
<term>Nitrides oxides</term>
<term>Nitriding</term>
<term>Photocatalysis</term>
<term>Photoelectron spectrometry</term>
<term>Pore size</term>
<term>Reflectance</term>
<term>Semiconductor materials</term>
<term>Surface area</term>
<term>Titanium nitride</term>
<term>Titanium oxide</term>
<term>Transition element compounds</term>
<term>Water</term>
<term>X ray</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Hydrogène</term>
<term>Ethanol</term>
<term>Photocatalyse</term>
<term>Nitruration</term>
<term>Nitrure de titane</term>
<term>Oxynitrure</term>
<term>Oxyde d'indium</term>
<term>Matériau composite</term>
<term>Eau</term>
<term>Semiconducteur</term>
<term>Catalyse hétérogène</term>
<term>Protection environnement</term>
<term>Composé de métal de transition</term>
<term>Oxyde de titane</term>
<term>Composé binaire</term>
<term>Ammoniac</term>
<term>Haute température</term>
<term>Catalyseur</term>
<term>Spectrométrie photoélectron</term>
<term>Rayon X</term>
<term>Diffraction RX</term>
<term>Facteur réflexion</term>
<term>Aire superficielle</term>
<term>Dimension pore</term>
<term>Distribution</term>
<term>Caractérisation</term>
<term>TiO2</term>
<term>O Ti</term>
</keywords>
<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Hydrogène</term>
<term>Matériau composite</term>
<term>Eau</term>
</keywords>
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<front><div type="abstract" xml:lang="en">Photocatalytic production of hydrogen gas from 20% ethanol-water was accomplished with Ti-In nitride composites. These materials were produced by nitriding a TiO<sub>2</sub>
 with ammonia at a high temperature, then adding In<sub>2</sub>
O<sub>3</sub>
 and further ammonolysis for different periods of time. The catalysts were very stable and continued to produce H<sub>2</sub>
 gas at 920 μmol h<sup>-1</sup>
 g<sup>-1</sup>
 for 50 h and accumulated 12.8 mmol H<sub>2</sub>
 gas. The water splitting photocatalytic reaction can be driven by UV-vis light, maximum producing H<sub>2</sub>
 gas at 1277 μmol h<sup>-1</sup>
 g<sup>-1</sup>
. It is critical that we understand how having high, stable activity is possible. We used XPS,X-ray (XRD), UV-vis diffuse reflectance spectrometry, and BET surface area and pore size distribution for further characterization.</div>
</front>
</TEI>
<inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0926-3373</s0>
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<fA03 i2="1"><s0>Appl. catal., B  Environ.</s0>
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<fA06><s2>3-4</s2>
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<fA08 i1="01" i2="1" l="ENG"><s1>Hydrogen from ethanol solution under UV-visible light. Photocatalysts produced by nitriding titanium nitride and indium oxide intimate mixtures to form Ti-In nitride composites</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>KUO (Yenting)</s1>
</fA11>
<fA11 i1="02" i2="1"><s1>KLABUNDE (Kenneth J.)</s1>
</fA11>
<fA14 i1="01"><s1>Department of Chemistry, Kansas State University</s1>
<s2>KS, 66506</s2>
<s3>USA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</fA14>
<fA20><s1>245-251</s1>
</fA20>
<fA21><s1>2011</s1>
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<fA43 i1="01"><s1>INIST</s1>
<s2>18840B</s2>
<s5>354000191588240060</s5>
</fA43>
<fA44><s0>0000</s0>
<s1>© 2011 INIST-CNRS. All rights reserved.</s1>
</fA44>
<fA45><s0>33 ref.</s0>
</fA45>
<fA47 i1="01" i2="1"><s0>11-0271100</s0>
</fA47>
<fA60><s1>P</s1>
</fA60>
<fA61><s0>A</s0>
</fA61>
<fA64 i1="01" i2="1"><s0>Applied catalysis. B, Environmental</s0>
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<fA66 i1="01"><s0>GBR</s0>
</fA66>
<fC01 i1="01" l="ENG"><s0>Photocatalytic production of hydrogen gas from 20% ethanol-water was accomplished with Ti-In nitride composites. These materials were produced by nitriding a TiO<sub>2</sub>
 with ammonia at a high temperature, then adding In<sub>2</sub>
O<sub>3</sub>
 and further ammonolysis for different periods of time. The catalysts were very stable and continued to produce H<sub>2</sub>
 gas at 920 μmol h<sup>-1</sup>
 g<sup>-1</sup>
 for 50 h and accumulated 12.8 mmol H<sub>2</sub>
 gas. The water splitting photocatalytic reaction can be driven by UV-vis light, maximum producing H<sub>2</sub>
 gas at 1277 μmol h<sup>-1</sup>
 g<sup>-1</sup>
. It is critical that we understand how having high, stable activity is possible. We used XPS,X-ray (XRD), UV-vis diffuse reflectance spectrometry, and BET surface area and pore size distribution for further characterization.</s0>
</fC01>
<fC02 i1="01" i2="X"><s0>001C01A03</s0>
</fC02>
<fC02 i1="02" i2="X"><s0>001C01F01</s0>
</fC02>
<fC02 i1="03" i2="X"><s0>001C01J08</s0>
</fC02>
<fC03 i1="01" i2="X" l="FRE"><s0>Hydrogène</s0>
<s2>NC</s2>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="ENG"><s0>Hydrogen</s0>
<s2>NC</s2>
<s5>01</s5>
</fC03>
<fC03 i1="01" i2="X" l="SPA"><s0>Hidrógeno</s0>
<s2>NC</s2>
<s5>01</s5>
</fC03>
<fC03 i1="02" i2="X" l="FRE"><s0>Ethanol</s0>
<s2>NK</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="ENG"><s0>Ethanol</s0>
<s2>NK</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>02</s5>
</fC03>
<fC03 i1="02" i2="X" l="SPA"><s0>Etanol</s0>
<s2>NK</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>02</s5>
</fC03>
<fC03 i1="03" i2="X" l="FRE"><s0>Photocatalyse</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="ENG"><s0>Photocatalysis</s0>
<s5>03</s5>
</fC03>
<fC03 i1="03" i2="X" l="SPA"><s0>Fotocatálisis</s0>
<s5>03</s5>
</fC03>
<fC03 i1="04" i2="X" l="FRE"><s0>Nitruration</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Nitriding</s0>
<s5>04</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Nitruración</s0>
<s5>04</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Nitrure de titane</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Titanium nitride</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Titanio nitruro</s0>
<s5>05</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Oxynitrure</s0>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Nitrides oxides</s0>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Oxinitruro</s0>
<s2>NA</s2>
<s5>06</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Oxyde d'indium</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Indium oxide</s0>
<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Indio óxido</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Matériau composite</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Composite material</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Material compuesto</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Eau</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Water</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Agua</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Semiconducteur</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Semiconductor materials</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Semiconductor(material)</s0>
<s5>10</s5>
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<s5>11</s5>
</fC03>
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<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Catálisis heterogénea</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Protection environnement</s0>
<s5>12</s5>
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<s5>12</s5>
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<s5>12</s5>
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<s5>15</s5>
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<s5>15</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Oxyde de titane</s0>
<s5>16</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Titanium oxide</s0>
<s5>16</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Titanio óxido</s0>
<s5>16</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Composé binaire</s0>
<s5>17</s5>
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<s5>17</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Compuesto binario</s0>
<s5>17</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Ammoniac</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>18</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Ammonia</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>18</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Amoníaco</s0>
<s2>NK</s2>
<s2>FX</s2>
<s5>18</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Haute température</s0>
<s5>19</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>High temperature</s0>
<s5>19</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Alta temperatura</s0>
<s5>19</s5>
</fC03>
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<s5>20</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG"><s0>Catalyst</s0>
<s5>20</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA"><s0>Catalizador</s0>
<s5>20</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE"><s0>Spectrométrie photoélectron</s0>
<s5>21</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG"><s0>Photoelectron spectrometry</s0>
<s5>21</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA"><s0>Espectrometría fotoelectrón</s0>
<s5>21</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE"><s0>Rayon X</s0>
<s5>22</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG"><s0>X ray</s0>
<s5>22</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA"><s0>Rayos X</s0>
<s5>22</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE"><s0>Diffraction RX</s0>
<s5>23</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG"><s0>X ray diffraction</s0>
<s5>23</s5>
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<fC03 i1="21" i2="X" l="SPA"><s0>Difracción RX</s0>
<s5>23</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE"><s0>Facteur réflexion</s0>
<s5>24</s5>
</fC03>
<fC03 i1="22" i2="X" l="ENG"><s0>Reflectance</s0>
<s5>24</s5>
</fC03>
<fC03 i1="22" i2="X" l="SPA"><s0>Coeficiente reflexión</s0>
<s5>24</s5>
</fC03>
<fC03 i1="23" i2="X" l="FRE"><s0>Aire superficielle</s0>
<s5>25</s5>
</fC03>
<fC03 i1="23" i2="X" l="ENG"><s0>Surface area</s0>
<s5>25</s5>
</fC03>
<fC03 i1="23" i2="X" l="SPA"><s0>Area superficial</s0>
<s5>25</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE"><s0>Dimension pore</s0>
<s5>26</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG"><s0>Pore size</s0>
<s5>26</s5>
</fC03>
<fC03 i1="24" i2="X" l="SPA"><s0>Dimensión poro</s0>
<s5>26</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE"><s0>Distribution</s0>
<s5>27</s5>
</fC03>
<fC03 i1="25" i2="X" l="ENG"><s0>Distribution</s0>
<s5>27</s5>
</fC03>
<fC03 i1="25" i2="X" l="SPA"><s0>Distribución</s0>
<s5>27</s5>
</fC03>
<fC03 i1="26" i2="X" l="FRE"><s0>Caractérisation</s0>
<s5>28</s5>
</fC03>
<fC03 i1="26" i2="X" l="ENG"><s0>Characterization</s0>
<s5>28</s5>
</fC03>
<fC03 i1="26" i2="X" l="SPA"><s0>Caracterización</s0>
<s5>28</s5>
</fC03>
<fC03 i1="27" i2="X" l="FRE"><s0>TiO2</s0>
<s4>INC</s4>
<s5>32</s5>
</fC03>
<fC03 i1="28" i2="X" l="FRE"><s0>O Ti</s0>
<s4>INC</s4>
<s5>33</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE"><s0>Alcanol</s0>
<s5>13</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Alkanol</s0>
<s5>13</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Alcanol</s0>
<s5>13</s5>
</fC07>
<fC07 i1="02" i2="X" l="FRE"><s0>Alcool</s0>
<s5>14</s5>
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<fC07 i1="02" i2="X" l="ENG"><s0>Alcohol</s0>
<s5>14</s5>
</fC07>
<fC07 i1="02" i2="X" l="SPA"><s0>Alcohol</s0>
<s5>14</s5>
</fC07>
<fN21><s1>185</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
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   |texte=   Hydrogen from ethanol solution under UV-visible light. Photocatalysts produced by nitriding titanium nitride and indium oxide intimate mixtures to form Ti-In nitride composites
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Hydrogen from ethanol solution under UV-visible light. Photocatalysts produced by nitriding titanium nitride and indium oxide intimate mixtures to form Ti-In nitride composites

Hydrogen from ethanol solution under UV-visible light. Photocatalysts produced by nitriding titanium nitride and indium oxide intimate mixtures to form Ti-In nitride composites

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